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I have many friends, some are businessm...

 I have many friends,        some are businessmen.

    A. of them B. from which   C. who of   D. of whom

 

 D 【详解】考查定语从句用法,不难看出后面是一非限制性定语从句修饰friends, 意思是在这些朋友中有一些是商人,表范围用of ,相当于some of my friends are businessmen.
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